Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction

doi:10.1039/c3cp51942b

科研成果详情

题名	Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction
作者	Xue, Yuhua1,2; Yu, Dingshan 2; Dai, Liming1,2; Wang, Ruigang 3; Li, Dingqiang 3; Roy, Ajit 4; Lu, Fan1; Chen, Hao 1; Liu, Yong1; Qu, Jia1
发表日期	2013-12-31
发表期刊	PHYSICAL CHEMISTRY CHEMICAL PHYSICS 影响因子和分区
语种	英语
原始文献类型	Article
其他关键词	HIGH ELECTROCATALYTIC ACTIVITY ; CARBON ; NITROGEN ; BORON ; NANOTUBES ; NITRIDE ; ARRAYS ; PHASE
摘要	Using a modified chemical vapor deposition (CVD) method, we have prepared a class of new graphene foams (GFs) doped with nitrogen, boron or both. Nitrogen-doped graphene foams (N-GFs) with a nitrogen doping level of 3.1 atom% were prepared by CVD of CH4 in the presence of NH3 while boron-doped graphene foams (B-GFs) with a boron doping level of 2.1 atom% were produced by using toluene and triethyl borate as a carbon and a boron source. On the other hand, graphene foams co-doped with nitrogen (4.5 atom%) and boron (3 atom%) (BN-GFs) were prepared by CVD using melamine diborate as the precursor. In all cases, scanning electron microscope (SEM) images revealed well-defined foam-like microstructures, while electrochemical measurements showed much higher electrocatalytic activities toward oxygen reduction reaction for the doped graphene foams than their undoped counterparts.
资助项目	Wenzhou Medical College, Case Western Reserve University; NSFNational Science Foundation (NSF) [CMMI-1000768]; AFOSRUnited States Department of DefenseAir Force Office of Scientific Research (AFOSR) [FA9550-10-1-0546, FA9550-12-1-0069]; AFOSR MURIUnited States Department of DefenseAir Force Office of Scientific Research (AFOSR)MURI [FA9550-12-1-0037]; AFRLUnited States Department of DefenseUS Air Force Research Laboratory [FA8650-07-D-5800]; UTC [11-S587-100-01-C1]; AFOSR-NBITUnited States Department of DefenseAir Force Office of Scientific Research (AFOSR) [FA2386-10-1-4071]; Zhejiang Innovation Team from Department of Education [T200917]; Ministry of Science and Technology of ChinaMinistry of Science and Technology, China [2009DFB30380]; Ministry of Education of ChinaMinistry of Education, China [IRT1077, 211069]; National Thousand Talents Program'' of China
出版者	ROYAL SOC CHEMISTRY
出版地	CAMBRIDGE
ISSN	1463-9076
EISSN	1463-9084
卷号	15 期号:29 页码:12220-12226
DOI	10.1039/c3cp51942b
页数	7
WOS类目	Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS研究方向	Chemistry ; Physics
WOS记录号	WOS:000321271300026
收录类别	SCIE ; PUBMED ; SCOPUS
URL	查看原文
PubMed ID	23770584
SCOPUSEID	2-s2.0-84879996082
ESI高被引论文	2020-01 ; 2020-03 ; 2020-05 ; 2020-09 ; 2020-11 ; 2021-01 ; 2021-03 ; 2021-05 ; 2021-07 ; 2021-09 ; 2021-11 ; 2022-01 ; 2022-03 ; 2022-05 ; 2022-09 ; 2022-11 ; 2023-01 ; 2023-03 ; 2023-05 ; 2023-07
通讯作者地址	[Dai, Liming]Institute of Advanced Materials for Nano-Bio Applications,School of Ophthalmology and Optometry,Wenzhou Medical College,270 Xueyuan Xi Road,China
Scopus学科分类	Physics and Astronomy (all);Physical and Theoretical Chemistry
引用统计	被引频次：257[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://kms.wmu.edu.cn/handle/3ETUA0LF/8699
专题	温州医科大学
通讯作者	Dai, Liming
作者单位	1.Institute of Advanced Materials for Nano-Bio Applications,School of Ophthalmology and Optometry,Wenzhou Medical College,270 Xueyuan Xi Road,China; 2.Center of Advanced Science and Engineering for Carbon (Case4Carbon),Department of Macromolecular Science and Engineering,Case Western Reserve University,United States; 3.Department of Chemistry,Youngstown State University,One University Plaza,United States; 4.Thermal Science and Materials Branch,Materials and Manufacturing Directorate,Air Force Research Laboratory,United States
推荐引用方式 GB/T 7714	Xue, Yuhua,Yu, Dingshan,Dai, Liming,et al. Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2013,15(29):12220-12226.
APA	Xue, Yuhua., Yu, Dingshan., Dai, Liming., Wang, Ruigang., Li, Dingqiang., ... & Qu, Jia. (2013). Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 15(29), 12220-12226.
MLA	Xue, Yuhua,et al."Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 15.29(2013):12220-12226.