Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction

doi:10.1039/c3cp51942b

科研成果详情

题名	Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction
作者	Xue, Yuhua1,2; Yu, Dingshan 2; Dai, Liming1,2; Wang, Ruigang 3; Li, Dingqiang 3; Roy, Ajit 4; Lu, Fan1; Chen, Hao1; Liu, Yong1; Qu, Jia1
发表期刊	PHYSICAL CHEMISTRY CHEMICAL PHYSICS 影响因子和分区
语种	英语
原始文献类型	Article
其他关键词	HIGH ELECTROCATALYTIC ACTIVITY ; CARBON ; NITROGEN ; BORON ; NANOTUBES ; NITRIDE ; ARRAYS ; PHASE
摘要	Using a modified chemical vapor deposition (CVD) method, we have prepared a class of new graphene foams (GFs) doped with nitrogen, boron or both. Nitrogen-doped graphene foams (N-GFs) with a nitrogen doping level of 3.1 atom% were prepared by CVD of CH4 in the presence of NH3 while boron-doped graphene foams (B-GFs) with a boron doping level of 2.1 atom% were produced by using toluene and triethyl borate as a carbon and a boron source. On the other hand, graphene foams co-doped with nitrogen (4.5 atom%) and boron (3 atom%) (BN-GFs) were prepared by CVD using melamine diborate as the precursor. In all cases, scanning electron microscope (SEM) images revealed well-defined foam-like microstructures, while electrochemical measurements showed much higher electrocatalytic activities toward oxygen reduction reaction for the doped graphene foams than their undoped counterparts.
资助项目	Wenzhou Medical College, Case Western Reserve University; NSFNational Science Foundation (NSF) [CMMI-1000768]; AFOSRUnited States Department of DefenseAir Force Office of Scientific Research (AFOSR) [FA9550-10-1-0546, FA9550-12-1-0069]; AFOSR MURIUnited States Department of DefenseAir Force Office of Scientific Research (AFOSR)MURI [FA9550-12-1-0037]; AFRLUnited States Department of DefenseUS Air Force Research Laboratory [FA8650-07-D-5800]; UTC [11-S587-100-01-C1]; AFOSR-NBITUnited States Department of DefenseAir Force Office of Scientific Research (AFOSR) [FA2386-10-1-4071]; Zhejiang Innovation Team from Department of Education [T200917]; Ministry of Science and Technology of ChinaMinistry of Science and Technology, China [2009DFB30380]; Ministry of Education of ChinaMinistry of Education, China [IRT1077, 211069]; National Thousand Talents Program'' of China
出版者	ROYAL SOC CHEMISTRY
出版地	CAMBRIDGE
ISSN	1463-9076
EISSN	1463-9084
卷号	15 期号:29 页码:12220-12226
DOI	10.1039/c3cp51942b
WOS类目	Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS研究方向	Chemistry ; Physics
WOS记录号	WOS:000321271300026
收录类别	SCIE ; PUBMED ; SCOPUS
发表日期	2013-12-31
URL	查看原文
Pubmed记录号	23770584
Scopus记录号	2-s2.0-84879996082
ESI高被引论文	2020-01 ; 2020-03 ; 2020-05 ; 2020-09 ; 2020-11 ; 2021-01 ; 2021-03 ; 2021-05 ; 2021-07 ; 2021-09 ; 2021-11 ; 2022-01 ; 2022-03 ; 2022-05 ; 2022-09 ; 2022-11 ; 2023-01 ; 2023-03 ; 2023-05 ; 2023-07
引用统计	被引频次：257[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://kms.wmu.edu.cn/handle/3ETUA0LF/8699
专题	眼视光学院（生物医学工程学院）、附属眼视光医院
通讯作者	Dai, Liming
作者单位	1.Wenzhou Med Coll, Inst Adv Mat Nanobio Applicat, Sch Ophthalmol & Optometry, Wenzhou 325027, Zhejiang, Peoples R China; 2.Case Western Reserve Univ, Ctr Adv Sci & Engn Carbon Case4Carbon, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA; 3.Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA; 4.Air Force Res Lab, Thermal Sci & Mat Branch, Mat & Mfg Directorate, Dayton, OH 45433 USA
第一作者单位	眼视光学院（生物医学工程学院）、附属眼视光医院
通讯作者单位	眼视光学院（生物医学工程学院）、附属眼视光医院
第一作者的第一单位	眼视光学院（生物医学工程学院）、附属眼视光医院; 眼视光学院（生物医学工程学院）、附属眼视光医院
推荐引用方式 GB/T 7714	Xue, Yuhua,Yu, Dingshan,Dai, Liming,et al. Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2013,15(29):12220-12226.
APA	Xue, Yuhua., Yu, Dingshan., Dai, Liming., Wang, Ruigang., Li, Dingqiang., ... & Qu, Jia. (2013). Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 15(29), 12220-12226.
MLA	Xue, Yuhua,et al."Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 15.29(2013):12220-12226.