题名 | Functionalization of Graphene Oxide with Polyhedral Oligomeric Silsesquioxane (POSS) for Multifunctional Applications |
作者 | |
发表期刊 | JOURNAL OF PHYSICAL CHEMISTRY LETTERS 影响因子和分区 |
语种 | 英语 |
原始文献类型 | Article |
关键词 | Amides Contact angle Glass transition Oligomers Superhydrophobicity Amide formation Carboxyl groups Functionalizations Functionalized Functionalized graphene Oxygen containing groups Polyhedral oligomeric silsesquioxanes Solution casting |
其他关键词 | SURFACES ; POLYMER |
摘要 | Through the amide formation between amine-functionalized polyhedral oligomeric silsesquioxane (POSS) and oxygen-containing groups (e.g., epoxy and carboxyl groups) in graphene oxide (GO), we have synthesized POSS-functionalized graphene nanosheets (POSS-graphene), which are highly soluble in various organic solvents attractive for multifunctional applications. Thin films from solution casting of the resultant POSS-graphene were found to show superhydrophobic properties with a water/air contact angle of similar to 15 degrees, while the superhydrophobic POSS-graphene powder could be used to construct liquid marbles. In addition, the POSS-graphene hybrids were also used as novel nanofillers to increase the glass transition temperature (T-g) and decompose temperature (T-d) for polymers. |
资助项目 | Wenzhou Medical College, Case Western Reserve University; Zhejiang Innovation Team from the Department of Education [T200917]; Zhejiang Department of Science and Technology [2009C13019]; Provincial Grant for High Level Medical Talents of Zhejiang; Ministry of Science and Technology of ChinaMinistry of Science and Technology, China [2009DFB30380]; Ministry of Education of ChinaMinistry of Education, China [IRT1077, 211069, 20103321120003]; National Thousand Talents Program of China, NSCF [81000663]; NSFC-NSF MWN [NSF-DMR 1106160]; AFOSRUnited States Department of DefenseAir Force Office of Scientific Research (AFOSR) |
出版者 | AMER CHEMICAL SOC |
出版地 | WASHINGTON |
ISSN | 1948-7185 |
EISSN | 1948-7185 |
卷号 | 3期号:12页码:1607-1612 |
DOI | 10.1021/jz3005877 |
页数 | 6 |
WOS类目 | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Atomic, Molecular & Chemical |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
WOS记录号 | WOS:000305662200006 |
收录类别 | SCIE ; EI ; SCOPUS |
发表日期 | 2012-06-21 |
EI入藏号 | 20122915249030 |
EI主题词 | Graphene |
URL | 查看原文 |
Scopus记录号 | 2-s2.0-84863701301 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://kms.wmu.edu.cn/handle/3ETUA0LF/1877 |
专题 | 眼视光学院(生物医学工程学院)、附属眼视光医院 |
通讯作者 | Chen, Hao |
作者单位 | 1.Wenzhou Med Coll, Sch Ophthalmol & Optometry, Inst Adv Mat Nanobio Applicat IAMNBA, Wenzhou 325027, Zhejiang, Peoples R China; 2.Wenzhou Med Coll, Hosp Eye, Wenzhou 325027, Zhejiang, Peoples R China; 3.Case Western Reserve Univ, Dept Macromol Sci & Engn, Ctr Adv Sci & Engn Carbon Case4Carbon, Cleveland, OH 44106 USA |
推荐引用方式 GB/T 7714 | Xue, Yuhua,Liu, Yong,Lu, Fan,et al. Functionalization of Graphene Oxide with Polyhedral Oligomeric Silsesquioxane (POSS) for Multifunctional Applications[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2012,3(12):1607-1612. |
APA | Xue, Yuhua, Liu, Yong, Lu, Fan, Qu, Jia, Chen, Hao, & Dai, Liming. (2012). Functionalization of Graphene Oxide with Polyhedral Oligomeric Silsesquioxane (POSS) for Multifunctional Applications. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 3(12), 1607-1612. |
MLA | Xue, Yuhua,et al."Functionalization of Graphene Oxide with Polyhedral Oligomeric Silsesquioxane (POSS) for Multifunctional Applications".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 3.12(2012):1607-1612. |
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