Functionalization of Graphene Oxide with Polyhedral Oligomeric Silsesquioxane (POSS) for Multifunctional Applications

doi:10.1021/jz3005877

科研成果详情

题名	Functionalization of Graphene Oxide with Polyhedral Oligomeric Silsesquioxane (POSS) for Multifunctional Applications
作者	Xue, Yuhua1,2; Liu, Yong1; Lu, Fan1; Qu, Jia1; Chen, Hao 1; Dai, Liming1,2
发表日期	2012-06-21
发表期刊	JOURNAL OF PHYSICAL CHEMISTRY LETTERS 影响因子和分区
语种	英语
原始文献类型	Article
关键词	Amides Contact angle Glass transition Oligomers Superhydrophobicity Amide formation Carboxyl groups Functionalizations Functionalized Functionalized graphene Oxygen containing groups Polyhedral oligomeric silsesquioxanes Solution casting
其他关键词	SURFACES ; POLYMER
摘要	Through the amide formation between amine-functionalized polyhedral oligomeric silsesquioxane (POSS) and oxygen-containing groups (e.g., epoxy and carboxyl groups) in graphene oxide (GO), we have synthesized POSS-functionalized graphene nanosheets (POSS-graphene), which are highly soluble in various organic solvents attractive for multifunctional applications. Thin films from solution casting of the resultant POSS-graphene were found to show superhydrophobic properties with a water/air contact angle of similar to 15 degrees, while the superhydrophobic POSS-graphene powder could be used to construct liquid marbles. In addition, the POSS-graphene hybrids were also used as novel nanofillers to increase the glass transition temperature (T-g) and decompose temperature (T-d) for polymers.
资助项目	Wenzhou Medical College, Case Western Reserve University; Zhejiang Innovation Team from the Department of Education [T200917]; Zhejiang Department of Science and Technology [2009C13019]; Provincial Grant for High Level Medical Talents of Zhejiang; Ministry of Science and Technology of ChinaMinistry of Science and Technology, China [2009DFB30380]; Ministry of Education of ChinaMinistry of Education, China [IRT1077, 211069, 20103321120003]; National Thousand Talents Program of China, NSCF [81000663]; NSFC-NSF MWN [NSF-DMR 1106160]; AFOSRUnited States Department of DefenseAir Force Office of Scientific Research (AFOSR)
出版者	AMER CHEMICAL SOC
出版地	WASHINGTON
ISSN	1948-7185
EISSN	1948-7185
卷号	3 期号:12 页码:1607-1612
DOI	10.1021/jz3005877
页数	6
WOS类目	Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Atomic, Molecular & Chemical
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS记录号	WOS:000305662200006
收录类别	SCIE ; EI ; SCOPUS
EI入藏号	20122915249030
EI主题词	Graphene
URL	查看原文
PubMed ID	26285716
SCOPUSEID	2-s2.0-84863701301
通讯作者地址	[Chen, Hao]Institute of Advanced Materials for Nano-Bio Applications (IAMNBA),School of Ophthalmology and Optometry and Eye Hospital,Wenzhou Medical College,270 Xueyuan West Road,China
Scopus学科分类	Materials Science (all);Physical and Theoretical Chemistry
TOP期刊	TOP期刊
引用统计	被引频次：212[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://kms.wmu.edu.cn/handle/3ETUA0LF/1877
专题	温州医科大学
通讯作者	Chen, Hao
作者单位	1.Institute of Advanced Materials for Nano-Bio Applications (IAMNBA),School of Ophthalmology and Optometry and Eye Hospital,Wenzhou Medical College,270 Xueyuan West Road,China; 2.Center of Advanced Science and Engineering for Carbon (Case4Carbon),Department of Macromolecular Science and Engineering,Case Western Reserve University,United States
推荐引用方式 GB/T 7714	Xue, Yuhua,Liu, Yong,Lu, Fan,et al. Functionalization of Graphene Oxide with Polyhedral Oligomeric Silsesquioxane (POSS) for Multifunctional Applications[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2012,3(12):1607-1612.
APA	Xue, Yuhua, Liu, Yong, Lu, Fan, Qu, Jia, Chen, Hao, & Dai, Liming. (2012). Functionalization of Graphene Oxide with Polyhedral Oligomeric Silsesquioxane (POSS) for Multifunctional Applications. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 3(12), 1607-1612.
MLA	Xue, Yuhua,et al."Functionalization of Graphene Oxide with Polyhedral Oligomeric Silsesquioxane (POSS) for Multifunctional Applications".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 3.12(2012):1607-1612.