Ferroelectricity and Thermochromism in a 2D Dion-Jacobson Organic-Inorganic Hybrid Perovskite

doi:10.1002/smll.202310529

科研成果详情

题名	Ferroelectricity and Thermochromism in a 2D Dion-Jacobson Organic-Inorganic Hybrid Perovskite
作者	Qiao, Wen-Cheng1; Qiao, Hongwei 2; Wang, Xue Lu 2; Xu, Haojie 3; Xu, Fanchen4; Sun, Zhihua 3; Gao, Hongchang1,4; Yao, Ye-Feng 2
发表日期	2023-12-26
发表期刊	SMALL 影响因子和分区
语种	英语
原始文献类型	Article ; Early Access ; Article in Press
关键词	2D perovskite Dion-Jacobson ferroelectricity thermochromism 2d perovskite Dion–jacobson Environmental stability Hot research topics Intelligent devices Multi channel Optoelectronics property Organic/Inorganic hybrids Pyridinium Thermochromism Dion–Jacobson
其他关键词	LEAD HALIDE PEROVSKITES
摘要	2D organic-inorganic hybrid perovskites (OIHPs) have become one of the hottest research topics due to their excellent environmental stability and unique optoelectronic properties. Recently, the ferroelectricity and thermochromism of 2D OIHPs have attracted increasing interests. Integrating ferroelectricity and thermochromism into perovskites can significantly promote the development of multichannel intelligent devices. Here, a novel 2D Dion-Jacobson OIHP of the formula (3AMP)PbI4 (where 3AMP is 3-(aminomethyl)pyridinium) is reported, which has a remarkable spontaneous polarization value (Ps) of 15.6 mu C cm-2 and interesting thermochromism. As far it is known, such a large Ps value is the highest for 2D OIHPs recorded so far. These findings will inspire further exploration and application of multifunctional perovskites. Coupling of ferroelectricity and optical properties has emerged as a captivating aspect of material research. This work demonstrates that (3AMP)PbI4 (3AMP = 3-(aminomethyl)pyridinium), a 2D Dion-Jacobson perovskite, not only boasts a remarkable spontaneous polarization, but also displays unique thermochromism. These findings will inspire further exploration and application of multifunctional perovskites.image
资助项目	National Natural Science Foundation of China; Xing-Fu-Zhi-Hua Foundation of ECNU; Scientific Research Center of Wenzhou Medical University; [22274052]; [22304133]
出版者	WILEY-V C H VERLAG GMBH
ISSN	1613-6810
EISSN	1613-6829
卷号	20 期号:24
DOI	10.1002/smll.202310529
页数	7
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS记录号	WOS:001135234900001
收录类别	SCIE ; PUBMED ; EI ; SCOPUS
在线发表日期	2023-12
EI入藏号	20235215294812
EI主题词	Perovskite
EI分类号	482.2 Minerals
URL	查看原文
PubMed ID	38148294
SCOPUSEID	2-s2.0-85180644470
通讯作者地址	[Gao, Hongchang]Oujiang Laboratory,Innovation Academy of Testing Technology,Scientific Research Center,Wenzhou Medical University,Wenzhou,325035,China ; [Yao, Ye-Feng]Physics Department and Shanghai Key Laboratory of Magnetic Resonance,School of Physics and Materials Science,East China Normal University,Shanghai,200062,China ; [Sun, Zhihua]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fujian,Fuzhou,350002,China
Scopus学科分类	Biotechnology;Chemistry (all);Biomaterials;Materials Science (all);Engineering (miscellaneous)
引用统计
文献类型	期刊论文
条目标识符	https://kms.wmu.edu.cn/handle/3ETUA0LF/209528
专题	附属第二医院_核磁共振室药学院（分析测试中心）其他_瓯江实验室
通讯作者	Sun, Zhihua; Gao, Hongchang; Yao, Ye-Feng
作者单位	1.Oujiang Laboratory,Innovation Academy of Testing Technology,Scientific Research Center,Wenzhou Medical University,Wenzhou,325035,China; 2.Physics Department and Shanghai Key Laboratory of Magnetic Resonance,School of Physics and Materials Science,East China Normal University,Shanghai,200062,China; 3.State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fujian,Fuzhou,350002,China; 4.Institute of Metabonomics and Medical NMR,School of Pharmaceutical Sciences,Wenzhou Medical University,Wenzhou,325035,China
第一作者单位	瓯江实验室
通讯作者单位	瓯江实验室
第一作者的第一单位	瓯江实验室
推荐引用方式 GB/T 7714	Qiao, Wen-Cheng,Qiao, Hongwei,Wang, Xue Lu,et al. Ferroelectricity and Thermochromism in a 2D Dion-Jacobson Organic-Inorganic Hybrid Perovskite[J]. SMALL,2023,20(24).
APA	Qiao, Wen-Cheng., Qiao, Hongwei., Wang, Xue Lu., Xu, Haojie., Xu, Fanchen., ... & Yao, Ye-Feng. (2023). Ferroelectricity and Thermochromism in a 2D Dion-Jacobson Organic-Inorganic Hybrid Perovskite. SMALL, 20(24).
MLA	Qiao, Wen-Cheng,et al."Ferroelectricity and Thermochromism in a 2D Dion-Jacobson Organic-Inorganic Hybrid Perovskite".SMALL 20.24(2023).