题名 | Improvements in mechanical, corrosion, and biocompatibility properties of Mg–Zr–Sr–Dy alloys via extrusion for biodegradable implant applications |
作者 | |
发表日期 | 2023 |
发表期刊 | Journal of Magnesium and Alloys; 影响因子和分区 |
语种 | 英语 |
原始文献类型 | Article |
关键词 | Corrosion Cytotoxicity Mg–Zr–Sr–Dy alloy Microstructure mechanical properties Mg-Zr-Sr-Dy alloy. |
其他关键词 | AZ31 MAGNESIUM ALLOY ; RARE-EARTH-ELEMENTS ; DYNAMIC RECRYSTALLIZATION ; TEXTURE EVOLUTION ; DEFORMATION-BEHAVIOR ; PURE MAGNESIUM ; IN-VITRO ; ELECTROCHEMICAL-BEHAVIOR ; PLASTIC-DEFORMATION ; HOT DEFORMATION |
摘要 | In this study, extrusion was performed on Mg‒Zr‒Sr‒Dy alloys for improving their mechanical, corrosion, and biocompatibility properties. Effects of extrusion and alloying elements on the microstructural characteristics, tensile and compressive strengths, corrosion behavior, and biocompatibility were investigated. The Mg‒Zr‒Sr‒Dy alloys were composed of an α-Mg matrix containing {101¯2} extension twins and secondary phases of intermetallic compounds Mg17Sr2 and Mg2Dy. Evolution of basal and rare earth (RE) textures was observed in the extruded alloys and an increase in Dy content to 2 wt.% resulted in texture randomization and strengthening of the RE component, mainly due to particle-stimulated nucleation and a change from discontinuous dynamic recrystallization to continuous dynamic recrystallization, which also led to an improved tension–compression yield asymmetry of 0.87. Extrusion of the alloys significantly enhanced their tensile and compressive properties due to improved distribution of alloying elements and formation of textures. Corrosion rates tested by hydrogen evolution testing, potentiodynamic polarization, and electrical impedance spectroscopy showed similar trends for each composition, and the lowest corrosion rate of 3.37 mmy−1 was observed for the Mg-1Zr-0.5Sr-1Dy in the potentiodynamic polarization testing. Dy2O3 was observed in the inner layers of the Mg(OH)2 protective films, whose protective efficacy was confirmed by charge-transfer and film resistances. A comparison among the minimum CRs observed in this study and previously studied as-cast Mg‒Zr‒Sr‒Dy and extruded Mg‒Zr‒Sr alloys, demonstrates that both the extrusion process and addition of Dy in Mg‒Zr‒Sr improved the CR. Similarly, extruded Mg–Zr–Sr–Dy alloys showed improved cell viability and adhesion of human osteoblast–like SaOS2 cells due to increased corrosion resistance and enhanced Sr distribution within the Mg matrix. |
资助项目 | Australian Research Council[DP170102557,FT160100252]; |
出版者 | KeAi Communications Co. |
ISSN | 2213-9567 |
卷号 | 11期号:10页码:3840-3865 |
DOI | 10.1016/j.jma.2023.09.031 |
页数 | 26 |
WOS类目 | Metallurgy & Metallurgical Engineering |
WOS研究方向 | Metallurgy & Metallurgical Engineering |
WOS记录号 | WOS:001124582700001 |
收录类别 | SCOPUS ; EI ; SCIE |
EI入藏号 | 20234515024509 |
EI主题词 | Rare earths |
EI分类号 | 461.9.1 Immunology ; 531 Metallurgy and Metallography ; 531.1 Metallurgy ; 539.1 Metals Corrosion ; 542.2 Magnesium and Alloys ; 547.2 Rare Earth Metals ; 549.2 Alkaline Earth Metals ; 802.2 Chemical Reactions ; 804.2 Inorganic Compounds ; 933.1 Crystalline Solids |
URL | 查看原文 |
SCOPUSEID | 2-s2.0-85175726370 |
通讯作者地址 | [Li, Yuncang]School of Engineering,RMIT University,Melbourne,3001,Australia |
Scopus学科分类 | Mechanics of Materials;Metals and Alloys |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://kms.wmu.edu.cn/handle/3ETUA0LF/184644 |
专题 | 口腔医学院、附属口腔医院 |
通讯作者 | Li, Yuncang |
作者单位 | 1.School of Engineering,RMIT University,Melbourne,3001,Australia; 2.School and Hospital of Stomatology,Wenzhou Medical University,Wenzhou,325027,China |
推荐引用方式 GB/T 7714 | Kiani, Faisal,Lin, Jixing,Munir, Khurram,et al. Improvements in mechanical, corrosion, and biocompatibility properties of Mg–Zr–Sr–Dy alloys via extrusion for biodegradable implant applications[J]. Journal of Magnesium and Alloys;,2023,11(10):3840-3865. |
APA | Kiani, Faisal, Lin, Jixing, Munir, Khurram, Wen, Cuie, & Li, Yuncang. (2023). Improvements in mechanical, corrosion, and biocompatibility properties of Mg–Zr–Sr–Dy alloys via extrusion for biodegradable implant applications. Journal of Magnesium and Alloys;, 11(10), 3840-3865. |
MLA | Kiani, Faisal,et al."Improvements in mechanical, corrosion, and biocompatibility properties of Mg–Zr–Sr–Dy alloys via extrusion for biodegradable implant applications".Journal of Magnesium and Alloys; 11.10(2023):3840-3865. |
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