题名 | Effects of imidazolium room temperature ionic liquids on the fluorescent properties of norfloxacin |
作者 | |
发表日期 | 2012-11 |
发表期刊 | LUMINESCENCE 影响因子和分区 |
语种 | 英语 |
原始文献类型 | Article |
关键词 | room temperature ionic liquid norfloxacin fluorescence sensitizing quenching |
其他关键词 | WAVELENGTH-DEPENDENT FLUORESCENCE ; OPTICAL-PROPERTIES ; SOLVENTS |
摘要 | The effects of 12 imidazolium room temperature ionic liquids (RTILs), including [C(n)mim]BF4, [C(n)mim]PF6, and [C(n)mim]Br (n=4, 6, 8, 10), on the fluorescent properties of norfloxacin were examined. The fluorescence intensity of norfloxacin at 0.1 mg/L in methanol significantly increased with the addition of [C(n)mim]BF4 and [C(n)mim]PF6 into the solvent at 0.1-15.0%. The sensitizing effect may result from the higher viscosity of the RTILs-methanol mixture solvent than that of the methanol itself. However, the quenching effect on fluorescence of norfloxacin was observed in [C(n)mim]Br-methanol solvent. The fluorescence intensities of norfloxacin decreased with an increase in the alkyl chain length of the alkyl substituents of the imidazolium ring of RTILs. The main interaction between the RTILs and norfloxacin is not by hydrogen bonding. The fact, that some RTILs can significantly sensitize fluorescence of norfloxacin, indicates that RTILs could be a group of promising solvents for development of sensitive spectrofluorimetric methods for determination of norfloxacin at ultra-trace levels in environmental samples. Copyright (C) 2011 John Wiley & Sons, Ltd. |
资助项目 | Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21077079, 31071115]; International Cooperation Project of Wenzhou City [H20100053, H20100054, H20090080]; Public Benefit Project of Zhejiang Province [2011C23112, 2011C37006] |
出版者 | WILEY |
出版地 | HOBOKEN |
ISSN | 1522-7235 |
EISSN | 1522-7243 |
卷号 | 27期号:6页码:495-500 |
DOI | 10.1002/bio.1382 |
页数 | 6 |
WOS类目 | Chemistry, Analytical |
WOS研究方向 | Chemistry |
WOS记录号 | WOS:000314529400010 |
收录类别 | SCIE ; PUBMED |
URL | 查看原文 |
PubMed ID | 22213460 |
通讯作者地址 | [Wang, Xuedong]Wenzhou Med Coll, Dept Environm Sci, Wenzhou 325035, Zhejiang, Peoples R China. |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://kms.wmu.edu.cn/handle/3ETUA0LF/17107 |
专题 | 公共卫生学院_环境科学系 |
通讯作者 | Wang, Xuedong |
作者单位 | 1.Wenzhou Med Coll, Dept Environm Sci, Wenzhou 325035, Zhejiang, Peoples R China; 2.Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou, Peoples R China |
第一作者单位 | 环境科学系 |
通讯作者单位 | 环境科学系 |
第一作者的第一单位 | 环境科学系 |
推荐引用方式 GB/T 7714 | Zou, Yujie,Wang, Huili,Wang, Wenwei,et al. Effects of imidazolium room temperature ionic liquids on the fluorescent properties of norfloxacin[J]. LUMINESCENCE,2012,27(6):495-500. |
APA | Zou, Yujie., Wang, Huili., Wang, Wenwei., Ma, Meiping., Wang, Ping., ... & Wang, Xuedong. (2012). Effects of imidazolium room temperature ionic liquids on the fluorescent properties of norfloxacin. LUMINESCENCE, 27(6), 495-500. |
MLA | Zou, Yujie,et al."Effects of imidazolium room temperature ionic liquids on the fluorescent properties of norfloxacin".LUMINESCENCE 27.6(2012):495-500. |
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