Separation and Determination of Triclosan and Bisphenol A in Water, Beverage, and Urine Samples by Dispersive Liquid-Liquid Microextraction Combined with Capillary Zone Electrophoresis-UV Detection

doi:10.5740/jaoacint.10-402

科研成果详情

题名	Separation and Determination of Triclosan and Bisphenol A in Water, Beverage, and Urine Samples by Dispersive Liquid-Liquid Microextraction Combined with Capillary Zone Electrophoresis-UV Detection
作者	Wang, Huili1; Zhang, Aina2; Wang, Wenwei 2; Zhang, Minghua2; Liu, Huanqiang 2; Wang, Xuedong 2
发表日期	2013-03
发表期刊	JOURNAL OF AOAC INTERNATIONAL 影响因子和分区
语种	英语
原始文献类型	Article
关键词	Beverages Capillary electrophoresis Electrolytes Liquids Organic solvents Phenols Sodium borate Back ground electrolyte Capillary zone electrophoresis Correlation coefficient Dispersive liquid-liquid microextraction Enrichment factors Environmental water Extraction solvents Optimum conditions
其他关键词	CHROMATOGRAPHY-MASS-SPECTROMETRY ; SOLID-PHASE MICROEXTRACTION ; BAR SORPTIVE EXTRACTION ; CARE PRODUCTS PPCPS ; ENDOCRINE-DISRUPTING COMPOUNDS ; IN-SITU DERIVATIZATION ; WIDELY USED BIOCIDE ; GAS-CHROMATOGRAPHY ; WASTE-WATER ; ENVIRONMENTAL WATER
摘要	Dispersive liquid-liquid microextraction combined with capillary zone electrophoresis-UV detection was developed for analyzing triclosan (TCS) and bisphenol A (BPA) in water, beverage, and urine samples. The factors influencing microextraction efficiencies, such as the kind and volume of extraction and dispersive solvent, the extraction time, and the salt effect, were optimized. A background electrolyte composed of 8 mM sodium tetraborate at pH 9.8 was used as the running buffer. Detection was performed at 214 nm. Under the optimum conditions (sample volume, 5.0 mL; extraction solvent, tetrachloroethane, 22.0 mu L; dispersive solvent, tetrahydrofuran, 1.0 mL; extraction time, fewer than 5 s; and without salt addition), the enrichment factors were 110.2 and 82.0 for TCS and BPA, respectively. The linear range was 0.02-2 mu g/mL with correlation coefficients of 0.9966-0.9969. LODs were in the range of 4.0-8.0 ng/mL. The environmental water, beverage, and urine samples (at spiking levels of 0.1 and 0.4 mu g/mL) were successfully analyzed by the proposed method; the recoveries compared to previous methods were in the range of 81.2-103.3%. As a result, this method can be successfully applied for the rapid and convenient determination of TCS and BPA in water, beverage, and urine samples.
资助项目	National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [31270548]; Key Project of Environmental Protection Department of Zhejiang Province [2012B014]; Project of Wenzhou City [H20100053, H20100054, S20100034]
出版者	AOAC INT
出版地	GAITHERSBURG
ISSN	1060-3271
卷号	96 期号:2 页码:459-465
DOI	10.5740/jaoacint.10-402
页数	43
WOS类目	Chemistry, Analytical ; Food Science & Technology
WOS研究方向	Chemistry ; Food Science & Technology
WOS记录号	WOS:000317870400033
收录类别	SCIE ; EI ; PUBMED ; SCOPUS
EI入藏号	20132016343745
EI主题词	Solvent extraction
URL	查看原文
PubMed ID	23767374
SCOPUSEID	2-s2.0-84877723001
通讯作者地址	[Wang, Xuedong]Wenzhou Med Coll, Sch Environm Sci & Publ Hlth, Wenzhou 325035, Peoples R China.
引用统计	被引频次：35[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://kms.wmu.edu.cn/handle/3ETUA0LF/13558
专题	检验医学院（生命科学学院、生物学实验教学中心）仁济学院_环境与公共卫生学部
通讯作者	Wang, Xuedong
作者单位	1.Wenzhou Med Coll, Coll Life Sci, Wenzhou 325035, Peoples R China; 2.Wenzhou Med Coll, Sch Environm Sci & Publ Hlth, Wenzhou 325035, Peoples R China
第一作者单位	检验医学院（生命科学学院、生物学实验教学中心）
通讯作者单位	环境与公共卫生学部
第一作者的第一单位	检验医学院（生命科学学院、生物学实验教学中心）
推荐引用方式 GB/T 7714	Wang, Huili,Zhang, Aina,Wang, Wenwei,et al. Separation and Determination of Triclosan and Bisphenol A in Water, Beverage, and Urine Samples by Dispersive Liquid-Liquid Microextraction Combined with Capillary Zone Electrophoresis-UV Detection[J]. JOURNAL OF AOAC INTERNATIONAL,2013,96(2):459-465.
APA	Wang, Huili, Zhang, Aina, Wang, Wenwei, Zhang, Minghua, Liu, Huanqiang, & Wang, Xuedong. (2013). Separation and Determination of Triclosan and Bisphenol A in Water, Beverage, and Urine Samples by Dispersive Liquid-Liquid Microextraction Combined with Capillary Zone Electrophoresis-UV Detection. JOURNAL OF AOAC INTERNATIONAL, 96(2), 459-465.
MLA	Wang, Huili,et al."Separation and Determination of Triclosan and Bisphenol A in Water, Beverage, and Urine Samples by Dispersive Liquid-Liquid Microextraction Combined with Capillary Zone Electrophoresis-UV Detection".JOURNAL OF AOAC INTERNATIONAL 96.2(2013):459-465.